Welding Tips and Tricks

I have accumulated all the necessary hardware to build my portable sawmill. The only thing left to buy is the structural steel. The main frame is 20 feet long with at least 6 cross braces. My concern is warpage along the entire length of the frame. Looking for suggestions. I am a hobbyist and have never tried anything on this scale before. All welding will be done with an ESAB stick welder.

Very best way is to eliminate most welding from the construction. You can weld sub-assemblies then bolt them to the frame rails.
I would start by redesigning you frame section to hopefully incorporate a single member, meaning one piece of stock, sufficiently stiff in the relevant directions, such a a t- bar, an angle section, a Jr. beam or a channel. Industry has moved to square or rectangular tube for frame sections because of simplicity of design due to it's resistance to bending in all directions as well as the simplicity of fabrication but the cost difference is significant and in your case it seems as if you need an edge to act as a rail.

If you must weld it, the basics are;
use as little weld as possible
skip weld
stagger your welds side to side
If you put equal amounts of weld on each side of a member, it will not bend.
Clamp the work securely to a good sized I or H beam.
Pre-bend the work in the opposite direction by inserting shims between the beam and the work.
Prepare to straighten the frame somewhat regardless, which is why I would bolt it together. As it is, you will likely need to straighten the stock before you weld it.